(From first published Diplomatic List – Nov. 1893)
DATE | NAME/MISSION |
| May 24, 1889 | Alfred Le Ghait, E.E. and M.P. |
| Jan. 1897 (List) | Maurice Joostens, Counselor of Legation (Not Charge d'Affaires) |
| Feb. 15, 1897 | Count G. de Lichtervelde, E.E. and M.P. |
| Aug. 1901 (List) | Baron Moncheur, Appt. E.E. and M.P. |
| Nov. 7, 1901 | E.E. and M.P. |
| Jun. 17, 1909 | E.de Cartier Marchienne, Charge d'Affaires a.i. |
| Nov. 18, 1909 | Count Conrad de Buisseret, E.E. and M.P. |
| Nov. 21, 1911 | E. Havenith, E.E. and M.P. |
| Apr. 23, 1917 | E. de Cartier Marchienne, E.E. and M.P. |
| May 12, 1920 | LEGATION RAISED TO EMBASSY |
| Sept. 13, 1919 | Baron de Cartier de Marchienne, Appt. Amb. E. and P. |
| May 12, 1920 | Amb. E. and P. |
| DEAN - Aug. 23, 1926 | |
| Oct. 26, 1927 | H.H. Prince Albert de Ligne, Amb. E. and P. |
| Apr. 2, 1931 | Paul May, Amb. E. and P. (DIED July 30, 1934) |
| Aug. 7, 1934 | H.H. Prince Eugene de Ligne, Charge d'Affaires a.i. |
| Jan. 18, 1935 | Count Robert van der Straten-Ponthoz, Amb. E.. and P. |
| DEAN - Nov. 16, 1944 | |
| Feb. 9, 1945 | Baron Silvercruys, Appt. Amb. E. and P. |
| March 8, 1945 | Amb. E. and P. |
| Aug. 11, 1959 | H.E. Louis Scheyven, Appt. Amb. E. and P. |
| Aug. 21, 1959 | Amb. E. and P. |
| Nov. 26, 1969 | H.E. Walter Loridan, Appt. Amb. E. and P. |
| Dec. 18, 1969 | Amb. E. and P. |
| May 31, 1974 | Mr. Herman Dehennin, Minister, Charge d'Affaires ad interim |
| Sept. 23, 1974 | Willy Van Cauwenberg, Appt. Amb. E. and P. |
| Oct. 4, 1974 | Amb. E. and P. |
| Aug. 1, 1979 | Count Francis de la Barre d1Erquelinnes, Minister, Charge d'Affaires ad interim |
| Sept. 25, 1979 | Raoul Schoumaker, Appt. Amb. E. and P. |
| Oct. 12, 1979 | Amb. E. and P. |
| Dec. 4, 1985 | Herman Dehennin, Appt. |
| Feb. 18, 1986 | Amb E and P. |
| Jan 25, 1991 | Juan Gassiers, Appt. |
| Feb. 19, 1991 | Amb. E. and P. |
| Oct. 3, 1994 | Andre Adam (copies of credentials) |
| Nov. 21, 1994 | Amb. E.. and P. (WH credentials) |
| Sept. 9, 1998 | Alexis Reyn, Appt. |
| Sept. 10, 1998 | Amb. E. and P. |
| Aug. 8, 2002 | Franciskus van Daele, Appt. |
| Sept. 25, 2002 | Amb. E. and P. |
| Dec. 29, 2006 | Dominicus Struye de Swielande, Appt. Amb. |
| Feb. 27, 2007 | Amb. E. and P. |
| Feb. 17, 2009 | Jan Josef Matthysen, Appt. Amb. |
| May 20, 2009 | Amb. E. and P. |
Special Terms* | |
