(From first published Diplomatic List – Nov 1893)
DATE | NAME/MISSION |
| January 22, 1891 | Sr. Salvador de Mendoca, E.E. and M.P. |
| June 1898 List | Manoel de Oliveira Lima , Charge d'Affaires a.i. |
| June 6, 1898 | J.F. de Assis-Brasil, E.E. and M.P. |
| December 28, 1904 | Alfredo de M. Gomes Ferreira, E.E. and M.P. ad interim |
| May 24, 1905 | LEGATION RAISED TO EMBASSY |
| May 24, 1905 | Joaquin Nabuco, Amb. E. and P. |
| (DIED January 17, 1910) | |
| January 17, 1910 | R. de Lima e Silva, Charge d'Affaires a.i. |
| May 1910 List | R. de Lima e Silva, Charge d'Affaires (NOT a.i.) |
| December 1910 List | Same as above - Charge d'Affaires a.i. (Date given as February 5) |
| June 16, 1911 | Domicio da Gama, Amb. E. and P. |
| March 1, 1920 | Augusto Cochrane de Alencar, Appt. Amb. E. and P. |
| May 26, 1920 | Amb. E. and P. |
| June 19, 1925 | S. Gurgel do Amaral, Amb. E. and P. |
| April 24, 1931 | R. de Lima e Silva, Amb. E. and P. |
| October 2, 1934 | Oswaldo Aranha, Amb. E. and P. |
| April 28, 1939 | Mario de Pimentel Brandao, Amb. E. and P. |
| February 28, 1939 | Carlos Martins Pereira e Sousa, Appt. Amb. E. and P. |
| March 8, 1939 | Amb. E. and P. (DEAN – November 7, 1945) |
| May 20, 1948 | Mauricio Nabuco, Appt. Amb. E. and P. |
| June 1, 1948 | Amb. E. and P. |
| November 1, 1951 | Afranio de Mello-Franco, Charge d'Affaires a.i. (Amb's name carried as absent until Mar 1952 List) |
| June 5, 1952 | Walther Moreira Salles, Appt. Amb. E. and P. |
| June 12, 1952 | Amb. E. and P. |
| August 14, 1953 | Sylvio Ribeiro de Carvalho, Charge d'Affaires a.i. (Amb's name not carried Oct. 1953 List Only) |
| October 8, 1953 | Joao Carlos Muniz, Appt. Amb. E. and P. |
| October 20, 1953 | Amb. E. and P. |
| July 16, 1956 | Ernani do Amaral Peixoto, Appt. Amb. E. and P. |
| July 18, 1956 | Amb. E. and P |
| July 13, 1959 | H.E. Walther Moreira Salles, Appt. Amb. E. and P. |
| July 23, 2959 | Amb. E. and P. |
| October 12, 1961 | Roberto de Oliveira Campos , Appt. Amb. E. and P. |
| October 18, 1961 | Amb. E. and P. |
| June 26, 1974 | Juracy Montenegro Magalhaes (Ret. Maj. Gen.) Appt. Amb. E. and P. |
| July 9, 1964 | Amb. E. and P. |
| January 31, 1966 | Vasco Tristao da Cunha, Appt. Amb. E. and P. |
| February 1, 1966 | Amb. E. and P. |
| February 14, 1969 | Mario GIBSON Barboza, Appt. Amb. E. and P. |
| February 21, 1969 | Amb. E. and P. |
| January 19, 1970 | Mozart Gurgel Valente, Jr., Appt. Amb. E. and P. |
| February 20, 1970 | Amb. E. and P (DIED December 19, 1970) |
| May 12, 1971 | Joao Augusto Araujo Castro, Appt. Amb. E. and P. |
| May 18, 1971 | Amb. E. and P. (DIED December 9, 1975) |
| Dec. 9, 1975 | Celso Diniz, Minister Counselor, Charge d'Affaires ad interim |
| June 10, 1976 | Joao Baptista Pinheiro, Appt. Amb. E. and P. |
| June 22, 1976 | Amb. E. and P. |
| June 15, 1979 | Antonio Francisco Azeredo da SILVEIRA, Appt. Amb. E. and P. |
| July 24, 1979 | Amb. E. and P. |
| September 16, 1983 | Sergio Correa, Affonso da, Costa Appt. Amb. E. and P. |
| October 13, 1983 | Amb. E. and P. |
| November 26, 1986 | Marcilio Marques Moreira, Appt. Amb. E. and P. |
| February 10, 1987 | Amb. E. and P. |
| August 28, 1991 | Rubens Ricupero, Appt. Amb. E. and P. |
| September 5, 1991 | Amb. E. and P. |
| November 15, 1993 | Paulo Tarso Flecha de Lima, Appt. Amb. E. and P. |
| December 9, 1993 | Amb. E. and P. |
| June 17, 1999 | Rubens Antonio Barbosa, Appt. Amb. E. and P. |
| August 10, 1999 | Amb. E. and P. |
| April 9, 2004 | Robert Abdenur, Appt. Amb. E. and P. |
| July 15, 2004 | Amb. E. and P. |
| February 23, 2007 | Antonio de Aguiar Patriota. Appt. Amb. E. and P. |
| February 27, 2007 | Amb. E. and P. |
| January 11, 2010 | Mauro Vieira, Appt. |
| February 24, 2010 | Amb. E. and P. |
Special Terms* | |
