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DATE | NAME/MISSION |
| Became Independent in 1975 | |
| February 1, 1985 | Joaquim Rafael Branco, Appt. |
| March 5, 1985 | Amb. E. and P. |
| March 10, 2006 | Ovidio Manuel Barbosa Pequeno, Appt. |
| March 13, 2006 | Amb. E. and P. |
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